Dataset: Global distribution of phosphate using high sensitivity techniques from data aggregated from many studies between 1988-2017

Final no updates expectedDOI: 10.1575/1912/bco-dmo.764704.1Version 1 (2019-04-17)Dataset Type:Other Field Results

Principal Investigator: Adam Martiny (University of California-Irvine)

BCO-DMO Data Manager: Shannon Rauch (Woods Hole Oceanographic Institution)


Project: Convergence: RAISE: Linking the adaptive dynamics of plankton with emergent global ocean biogeochemistry (Ocean Stoichiometry)


Abstract

Surface ocean phosphate is commonly below the standard analytical detection limit (~100 nM) leading to an incomplete picture of the global variation and biogeochemical role of phosphate. This dataset represents a global compilation of phosphate measured using high-sensitivity methods including magnesium induced precipitation (MAGIC), liquid waveguide cell (LWCC), and solid phase extraction (SPE) methods. We compiled data from 42 major cruises covering all oligotrophic regions using high-sensitiv...

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For complete methdology, see Martiny et al, (2019).

Data have been aggregated from many studies. Procedures and methodology include the following:
Sampling procedures: Liquid samples taken from the Rosette or Underway System. Samples are either processed fresh or stored frozen until processing. Some samples are pre-filtered.

Methodology: High sensitivity dissolved phosphate measurements done using either Liquid Waveguide Cells, magnesium induced precipitation (MAGIC), or solid phase extraction.

Many instruments were used but the main procedures include: MAGIC (Karl & Tien, 1992), LWCC - Liquid Waveguide cells (Li & Hansell, 2008), and Solid phase extraction (Ma, Yuan, & Yuan, 2017).


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Results

Martiny, Adam C., Michael W Lomas, Weiwei Fu, Philip W Boyd, Yuh-ling L Chen, Gregory A Cutter, Michael J Ellwood, Ken Furuya, Fuminori Hashihama, Jota Kanda, David M Karl, Taketoshi Kodama, Qian P Li, Jian Ma, Thierry Moutin, E Malcolm S Woodward, and J Keith Moore. (2019.) Biogeochemical controls of surface ocean phosphate. Science Advances, Vol. 5, no. 8, eaax0341. DOI: 10.1126/sciadv.aax0341
Methods

Karl, D. M., & Tien, G. (1992). MAGIC: A sensitive and precise method for measuring dissolved phosphorus in aquatic environments. Limnology and Oceanography, 37(1), 105–116. doi:10.4319/lo.1992.37.1.0105
Methods

Li, Q. P., & Hansell, D. A. (2008). Intercomparison and coupling of magnesium-induced co-precipitation and long-path liquid-waveguide capillary cell techniques for trace analysis of phosphate in seawater. Analytica Chimica Acta, 611(1), 68–72. doi:10.1016/j.aca.2008.01.074
Methods

Ma, J., Yuan, Y., & Yuan, D. (2017). Underway analysis of nanomolar dissolved reactive phosphorus in oligotrophic seawater with automated on-line solid phase extraction and spectrophotometric system. Analytica Chimica Acta, 950, 80–87. doi:10.1016/j.aca.2016.11.029