Dataset: Concentrations of DMS, DMSPp, DMSPd, & DMSOd in relation to ocean acidification [H+] during the KOSMOS 2014 mesocosm experiment off Gran Canaria

Final no updates expectedDOI: 10.1575/1912/bco-dmo.769302.1Version 1 (2019-06-03)Dataset Type:Other Field Results

Principal Investigator, Contact: Stephen D. Archer (Bigelow Laboratory for Ocean Sciences)

Co-Principal Investigator: Peter Countway (Bigelow Laboratory for Ocean Sciences)

Co-Principal Investigator: Patricia A. Matrai (Bigelow Laboratory for Ocean Sciences)

BCO-DMO Data Manager: Shannon Rauch (Woods Hole Oceanographic Institution)


Project: Ocean Acidification: Influence of Ocean Acidification on Biotic Controls of DMS Emissions (OA on DMS)


Abstract

Concentrations of DMS, DMSPp, DMSPd, & DMSOd in relation to ocean acidification [H+] during the KOSMOS 2014 mesocosm experiment off Gran Canaria. The full experiment took place from 23rd September to 25th November 2014.

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From Archer et al. (2018): The mesocosm experiment was conducted in Gando Bay, on the east coast of Gran Canaria (27° 55' 41" N, 15° 21' 55" W) in the subtropical North Atlantic. Sample processing, analysis and further experiments were conducted in the laboratories of Plataforma Oceánica de Canarias (PLOCAN), Gran Canaria. The full experiment took place from 23rd September to 25th November 2014. The design and deployment of the Kiel Off-Shore Mesocosms for future Ocean Simulations (KOSMOS) facility has previously been described in detail (Riebesell et al., 2013).

Sampling and analytical procedures: The experimental set-up and sampling of the mesocosms is described in Taucher et al. (2017).

Procedures for the analysis of reduced sulfur compounds was based on purge-and-cryotrap approaches linked to a gas chromatograph with either flame FPD or mass spectrometric detector and is described in Archer et al. (2018).

Quantification of dissolved DMSO [DMSOd] closely followed the protocol of del Valle et al. (2007) and is reported in Archer et al. (2018).

Additional data from the experiment has been deposited on the PANGEA database: https://www.pangaea.de/?q=KOSMOS_2014


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Methods

Archer, S. D., Suffrian, K., Posman, K. M., Bach, L. T., Matrai, P. A., Countway, P. D., … Riebesell, U. (2018). Processes That Contribute to Decreased Dimethyl Sulfide Production in Response to Ocean Acidification in Subtropical Waters. Frontiers in Marine Science, 5. doi:10.3389/fmars.2018.00245
Methods

Del Valle, D. A., Kieber, D. J., John, B., & Kiene, R. P. (2007). Light-stimulated production of dissolved DMSO by a particle-associated process in the Ross Sea, Antarctica. Limnology and Oceanography, 52(6), 2456–2466. doi:10.4319/lo.2007.52.6.2456
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Lueker, T. J., Dickson, A. G., & Keeling, C. D. (2000). Ocean pCO2 calculated from dissolved inorganic carbon, alkalinity, and equations for K1 and K2: validation based on laboratory measurements of CO2 in gas and seawater at equilibrium. Marine Chemistry, 70(1-3), 105–119. doi:10.1016/s0304-4203(00)00022-0
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Pierrot, D. E. Lewis,and D. W. R. Wallace. 2006. MS Excel Program Developed for CO2 System Calculations. ORNL/CDIAC-105a. Carbon Dioxide Information Analysis Center, Oak Ridge National Laboratory, U.S. Department of Energy, Oak Ridge, Tennessee. doi: 10.3334/CDIAC/otg.CO2SYS_XLS_CDIAC105a.
Methods

Riebesell, U., Czerny, J., von Bröckel, K., Boxhammer, T., Büdenbender, J., Deckelnick, M., … Schulz, K. G. (2013). Technical Note: A mobile sea-going mesocosm system – new opportunities for ocean change research. Biogeosciences, 10(3), 1835–1847. doi:10.5194/bg-10-1835-2013