Dataset: Radium isotope (223Ra, 224Ra, and 226Ra) measurements from CTD and underway water samples collected on R/V Endeavor cruise EN640 from June-July 2019

Final no updates expectedDOI: 10.26008/1912/bco-dmo.846802.1Version 1 (2021-03-24)Dataset Type:Cruise Results

Principal Investigator, Contact: Richard N. Peterson (Coastal Carolina University)

Co-Principal Investigator: Joseph Montoya (Georgia Institute of Technology)

Co-Principal Investigator: Ajit Subramaniam (Lamont-Doherty Earth Observatory)

BCO-DMO Data Manager: Shannon Rauch (Woods Hole Oceanographic Institution)


Project: Collaborative Research: Impact of the Amazon River Plume on Nitrogen Availability and Planktonic Food Web Dynamics in the Western Tropical North Atlantic (Amazon River Plume Nitrogen)


Abstract

This dataset includes radium isotope (223Ra, 224Ra, and 226Ra) measurements from CTD and underway water samples collected on R/V Endeavor cruise EN640 from June-July 2019.

Water samples for radium isotope analysis were collected from both the ship's clean underway intake system ('U' designator in data) and niskin bottles attached to the CTD rosette ('C' designator in data). Salinity data were derived from the ship's clean underway intake system with SBE 21 SEACAT Thermosaliograph. Water samples were filtered through 47 mm GFF filters (unless otherwise noted), then passed slowly through 25 g (dry) acrylic fibers impregnated with MnO2 (Moore, 1976). Fibers were then washed 10x with Ra-free freshwater to remove salts and dried to a mass between 35 and 57 g for optimal humidity levels (Sun and Torgersen, 1998). Fibers were then immediately counted on a Radium Delayed Coincidence Counter (RaDeCC; Moore and Arnold, 1996) for total Ra-224 and Ra-223. Roughly 3 weeks later, fibers were counted again for supported Ra-224. Thus, excess ('XS') Ra-224 is the difference between total and supported Ra-224 measurements. Ra-226 activities were then measured on a radon emanation line as per Peterson et al. (2009).

Minimum detectable activities (dpm/100L) are calculated based on Currie (1968). Any measured values lower than the minimum detectable activity is labeled 'BD' in the dataset.


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Related Publications

Methods

Currie, L. A. (1968). Limits for qualitative detection and quantitative determination. Application to radiochemistry. Analytical Chemistry, 40(3), 586–593. doi:10.1021/ac60259a007
Methods

Moore, W. S. (1976). Sampling 228Ra in the deep ocean. Deep Sea Research and Oceanographic Abstracts, 23(7), 647–651. doi:10.1016/0011-7471(76)90007-3
Methods

Moore, W. S., & Arnold, R. (1996). Measurement of 223Ra and224Ra in coastal waters using a delayed coincidence counter. Journal of Geophysical Research: Oceans, 101(C1), 1321–1329. doi:10.1029/95jc03139
Methods

Peterson, R. N., Burnett, W. C., Dimova, N., & Santos, I. R. (2009). Comparison of measurement methods for radium-226 on manganese-fiber. Limnology and Oceanography: Methods, 7(2), 196–205. doi:10.4319/lom.2009.7.196
Methods

Sun, Y., & Torgersen, T. (1998). The effects of water content and Mn-fiber surface conditions on measurement by emanation. Marine Chemistry, 62(3-4), 299–306. doi:10.1016/s0304-4203(98)00019-x