Dataset: Bottle chemistry data from hydrothermal vents sampled by CTD rosette during R/V Atlantis cruise AT37-12 in April and May 2017

Final no updates expectedDOI: 10.26008/1912/bco-dmo.889539.1Version 1 (2023-02-13)Dataset Type:Cruise Results

Principal Investigator, Contact: Andrew R. Babbin (Massachusetts Institute of Technology)

Co-Principal Investigator: Ryan Woosley (Massachusetts Institute of Technology)

Student: Timur Cinay (Massachusetts Institute of Technology)

BCO-DMO Data Manager: Taylor Heyl (Woods Hole Oceanographic Institution)


Project: Collaborative Research: Environmental Drivers of Chemoautotrophic Carbon Production at Deep-Sea Hydrothermal Vents - Comparative Roles of Oxygen and Nitrate (vent O2 NO3 roles)


Abstract

The Eastern Tropical North Pacific (ETNP), like the other marine oxygen deficient zones (ODZs), is characterized by an anoxic water column, nitrite accumulation at the anoxic core, and fixed nitrogen loss via nitrite reduction to N2O and N2 gases. Here, we constrain the relative contribution of biogeochemical processes to observable features such as the secondary nitrite maximum (SNM) and local pH maximum by simultaneous measurement of inorganic nitrogen and carbon species. Bottle chemistry data...

Show more

This dataset represents bottle chemistry (Nitrite, pH, alkalinity, and oxygen) data that were collected from discrete depths by CTD rosette during the AT37-12 cruise on R/V Atlantis in the southern part of the Eastern Tropical North Pacific (ETNP) in April–May 2017. Samples were acquired using a 24-bottle CTD rosette equipped with temperature, salinity, pressure, and oxygen sensors at 8 stations. We measured nitrite using the Griess method, Nitrate by chemiluminescence detection via vanadium reduction, pH by colorimetric determination, and Total Alkalinity by titration.

Nitrite was measured using an Ocean Optics QEPRO spectrophotometer with a 10-centimeter Starna flow-through quartz cell. Nitrate is reported as the difference from the total nitrogen oxides measured with a Teledyne T200 NOx analyzer with a custom front end for vanadium reduction and nitrite measurement. pH was measured using an Agilent 8454 spectrophotometer with a custom front end for automated syringe injection. Total Alkalinity was measured using a custom total alkalinity titrator built by the lab of Andrew Dickson at UCSD-Scripps Institute for Oceanography.

Further details in Cinay et al. 2022, Global Biogeochemical Cycles


Related Datasets

No Related Datasets

Related Publications

Results

Cinay, T., Dumit, D., Woosley, R. J., Boles, E. L., Kwiecinski, J. V., Mullen, S., Tamasi, T. J., Wolf, M. J., Kelly, C. L., Travis, N. M., Casciotti, K. L., & Babbin, A. R. (2022). Coincident Biogenic Nitrite and pH Maxima Arise in the Upper Anoxic Layer in the Eastern Tropical North Pacific. Global Biogeochemical Cycles, 36(12). Portico. https://doi.org/10.1029/2022gb007470