Dataset: Measurements of Radium isotopes (Ra-224 and Ra-223) collected aboard the R/V Falkor cruise FK190211 in the Guaymas Basin of the Gulf of California from February to March 2019.

This dataset has not been validatedPreliminary and in progressVersion 1 (2024-04-30)Dataset Type:Cruise Results

Co-Principal Investigator, Contact: Richard N. Peterson (Coastal Carolina University)


Project: Collaborative Research: Microbial Carbon cycling and its interactions with Sulfur and Nitrogen transformations in Guaymas Basin hydrothermal sediments (Guaymas Basin Interactions)


Abstract

During cruise FK190211 aboard the R/V Falkor in the Guaymas Basin within the Gulf of California, water samples were analyzed for short-lived radium isotopes (Ra-224 and Ra-223). This cruise occurred during February-March 2019. The short-lived radium isotopes can be used as an indicator of subsurface fluids discharged into the water column, and when coupled with nutrient and microbial analyses, can yield insight into cycling rates within the water column.

Water samples for radium isotope analysis were collected from both niskin bottles attached to the CTD rosette (‘C’ designator in data sheet) and from niskin bottles attached to the remotely operated vehicle (ROV).  Water samples were filtered through 47 mm GFF filters (unless otherwise noted), then passed slowly through 25 g (dry) acrylic fibers impregnated with MnO2 (Moore, 1976).  Fibers were then washed 10x with Ra-free freshwater to remove salts and dried to a mass between 35 and 57 g for optimal humidity levels (Sun and Torgersen, 1998).  Fibers were then immediately counted on a Radium Delayed Coincidence Counter (RaDeCC; Moore and Arnold, 1996) for total Ra-224 and Ra-223.  Roughly 3 weeks later, fibers were counted again for supported Ra-224.  Thus, excess (‘XS’) Ra-224 is the difference between total and supported Ra-224 measurements. 

Radium isotopes were analyzed with a Radium Delayed Coincidence Counter (Moore and Arnold, 1996).  This system was calibrated to standard MnO2 prepared from NIST-traceable solutions of Th-232 and Ac-227 (with daughters in equilibrium).


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Related Publications

Methods

Currie, L. A. (1968). Limits for qualitative detection and quantitative determination. Application to radiochemistry. Analytical Chemistry, 40(3), 586–593. doi:10.1021/ac60259a007
Methods

Moore, W. S. (1976). Sampling 228Ra in the deep ocean. Deep Sea Research and Oceanographic Abstracts, 23(7), 647–651. doi:10.1016/0011-7471(76)90007-3
Methods

Moore, W. S., & Arnold, R. (1996). Measurement of 223Ra and224Ra in coastal waters using a delayed coincidence counter. Journal of Geophysical Research: Oceans, 101(C1), 1321–1329. doi:10.1029/95jc03139
Methods

Peterson, R. N., Burnett, W. C., Dimova, N., & Santos, I. R. (2009). Comparison of measurement methods for radium-226 on manganese-fiber. Limnology and Oceanography: Methods, 7(2), 196–205. doi:10.4319/lom.2009.7.196
Methods

Sun, Y., & Torgersen, T. (1998). The effects of water content and Mn-fiber surface conditions on measurement by emanation. Marine Chemistry, 62(3-4), 299–306. doi:10.1016/s0304-4203(98)00019-x