Dataset: Particulate Carbon Concentrations and Stable Carbon Isotopes in Marine Particles Captured by In Situ Mclane Pumps at Cocos Ridge Coco Ridge (Eastern Equatorial Pacific) during cruise SR2113 between November - December 2021

Final no updates expectedDOI: 10.26008/1912/bco-dmo.925258.1Version 1 (2024-05-10)Dataset Type:Other Field Results

Principal Investigator: Jess F. Adkins (California Institute of Technology)

Principal Investigator: William M. Berelson (University of Southern California)

Principal Investigator, Contact: Sijia Dong (California Institute of Technology)

Scientist: Frank J. Pavia (California Institute of Technology)

BCO-DMO Data Manager: Karen Soenen (Woods Hole Oceanographic Institution)


Project: Collaborative Research: New approaches to study calcium carbonate dissolution on the sea floor and its impact on paleo-proxy interpretations (CDISP 2021)


Abstract

This dataset includes particulate carbon concentrations and isotopes collected in December, 2021. Suspended particles are collected at 4 different stations near Cocos Ridge, at two different size fractions using Mclane pumps. The two size fractions are large size fraction (LSF) that is >51 um, and small size fraction (SSF) that is 0.5 -- 51 um. Concentrations and stable carbon isotopes of particulate inorganic carbon (PIC) and total carbon (TC) are measured and reported. PIC content are measure...

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Dual-flowpath in situ pumps (McLane WTS-6-1-142LVUP) were deployed at targeted depths for 3-5 hours at 4 stations (CR1, CR2, CR3 and CR5), with approximately 1400 L seawater flowing through the filters. The filter holders had two stages for two size fractions and multiple baffle systems designed to ensure even particle distribution and prevent particle loss (Bishop et al. 2012; Lam et al. 2018).

Samples analyzed in this study were collected on the filter holder/flowpath which was loaded with a 51 um Sefar polyester mesh prefilter followed by a paired 0.5 um Glass Fiber Filter (GF/F) (Advantec GC-50, LOT No. 70207718, 142 mm diameter). The 51 um prefilter was underlain by a 150 um Sefar polyester mesh support filter to facilitate filter handling. The GF/F filters were pre-combusted at 450 C overnight to remove any potential organic matter. In this dataset, data reported from the 51 um prefilter were referred to as “LSF” to indicate large size fraction (> 51 um); data reported from the main filters (GF/F, 0.5 – 51 um) were referred to as “SSF” to indicate small size fraction. Upon recovery of the pumps, the 51 um prefilters were subsampled into slices of 1/4 or 1/2 of the total filter, and the LSF particles were rinsed onto 26 mm diameter Glass Fiber Filters. The LSF and SSF GF/Fs were then dried at room temperature for 24 h. At CR, 1/4 of each LSF and SSF filter was used for Particulate Inorganic Carbon (PIC) concentration and d13C measurements; 1/4 of each LSF and a circle of 26 mm diameter of the SSF was used for Total Carbon (TC) concentration and d13C measurements.

For each pump cast, a dipped blank sample was collected, and all concentration calculations were corrected by subtracting the dipped blank signal to remove the potential effect of DOC absorbed onto the filters. The effect of DOC on the isotopic values of filter TC is neglected because the amount of DOC is trivial compared to POC on the filters.


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Results

Submitted to GCA: Cetiner J. E. P., Berelson W. M., Rollins N. E., Liu X., Pavia, F. J., Waldeck, A. R., Dong S., Fleger, K., Barnhart H. A., Quinan, M., Wani, R., Rafter, P. A., Jacobson, A. D., Byrne R. H. and Adkins J. F. Carbonate dissolution fluxes in deep-sea sediments as determined from in situ porewater profiles in a transect across the saturation horizon
Methods

Bishop, J. K. B., Lam, P. J., & Wood, T. J. (2012). Getting good particles: Accurate sampling of particles by large volume in-situ filtration. Limnology and Oceanography: Methods, 10(9), 681–710. doi:10.4319/lom.2012.10.681
Methods

Lam, P. J., Lee, J.-M., Heller, M. I., Mehic, S., Xiang, Y., & Bates, N. R. (2018). Size-fractionated distributions of suspended particle concentration and major phase composition from the U.S. GEOTRACES Eastern Pacific Zonal Transect (GP16). Marine Chemistry, 201, 90–107. doi:10.1016/j.marchem.2017.08.013